Wednesday 11 January 2012

Molar Volume

Molar Volume
-Molar volume of a gas at STP gases expand and contract with changes in temperature and pressure.
-We have a standard condition to compare volume of gases called STP(Standard Temperature Pressure)

  •            STP = 1 atmosphere at pressure and a temp at 0 degrees celsius or 273.15K
  •            At STP 1 mole of gas occupies 22.4L, thus we can create the conversion factors 
    • 22.4L/mole of gas  OR mole of gas/22.4L
EXAMPLE

Calculate the volume occupied by 3.4g of ammonia at STP.

SOLUTION
Molar mass of ammonia (NH^3) = (1x14) + (3x1) = 173 mol - - - - - - moles of ammonia = 3.4 g x 1 mole / 17g

Molar volume = 22.4L
                       = 0.2 moles x 22.4L/mole
                       = 4.5L
Volume of occupied by 3.4 g of ammonia at STP = 4.5L

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